Improving Processing and Performance of Pure Lignin Carbon Fibers through Hardwood and Herbaceous Lignin Blends.
Identifieur interne : 001338 ( Main/Exploration ); précédent : 001337; suivant : 001339Improving Processing and Performance of Pure Lignin Carbon Fibers through Hardwood and Herbaceous Lignin Blends.
Auteurs : Omid Hosseinaei [États-Unis] ; David P. Harper [États-Unis] ; Joseph J. Bozell [États-Unis] ; Timothy G. Rials [États-Unis]Source :
- International journal of molecular sciences [ 1422-0067 ] ; 2017.
Descripteurs français
- KwdFr :
- MESH :
- composition chimique : Bois, Carbone, Lignine.
- Fibre de carbone, Résistance à la traction, Spectroscopie par résonance magnétique, Thermodynamique.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Carbon, Lignin.
- chemical : Carbon Fiber.
- chemistry : Wood.
- Magnetic Resonance Spectroscopy, Tensile Strength, Thermodynamics.
Abstract
Lignin/lignin blends were used to improve fiber spinning, stabilization rates, and properties of lignin-based carbon fibers. Organosolv lignin from Alamo switchgrass (Panicum virgatum) and yellow poplar (Liriodendron tulipifera) were used as blends for making lignin-based carbon fibers. Different ratios of yellow poplar:switchgrass lignin blends were prepared (50:50, 75:25, and 85:15 w/w). Chemical composition and thermal properties of lignin samples were determined. Thermal properties of lignins were analyzed using thermogravimetric analysis and differential scanning calorimetry. Thermal analysis confirmed switchgrass and yellow poplar lignin form miscible blends, as a single glass transition was observed. Lignin fibers were produced via melt-spinning by twin-screw extrusion. Lignin fibers were thermostabilized at different rates and subsequently carbonized. Spinnability of switchgrass lignin markedly improved by blending with yellow poplar lignin. On the other hand, switchgrass lignin significantly improved thermostabilization performance of yellow poplar fibers, preventing fusion of fibers during fast stabilization and improving mechanical properties of fibers. These results suggest a route towards a 100% renewable carbon fiber with significant decrease in production time and improved mechanical performance.
DOI: 10.3390/ijms18071410
PubMed: 28671571
PubMed Central: PMC5535902
Affiliations:
Links toward previous steps (curation, corpus...)
Le document en format XML
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Harper</name><affiliation wicri:level="2"><nlm:affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. dharper4@utk.edu.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996</wicri:regionArea><placeName><region type="state">Tennessee</region></placeName></affiliation></author><author><name sortKey="Bozell, Joseph J" sort="Bozell, Joseph J" uniqKey="Bozell J" first="Joseph J" last="Bozell">Joseph J. Bozell</name><affiliation wicri:level="2"><nlm:affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. jbozell@utk.edu.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996</wicri:regionArea><placeName><region type="state">Tennessee</region></placeName></affiliation></author><author><name sortKey="Rials, Timothy G" sort="Rials, Timothy G" uniqKey="Rials T" first="Timothy G" last="Rials">Timothy G. Rials</name><affiliation wicri:level="2"><nlm:affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. trials@utk.edu.</nlm:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996</wicri:regionArea><placeName><region type="state">Tennessee</region></placeName></affiliation></author></analytic><series><title level="j">International journal of molecular sciences</title><idno type="eISSN">1422-0067</idno><imprint><date when="2017" type="published">2017</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carbon (chemistry)</term><term>Carbon Fiber (MeSH)</term><term>Lignin (chemistry)</term><term>Magnetic Resonance Spectroscopy (MeSH)</term><term>Tensile Strength (MeSH)</term><term>Thermodynamics (MeSH)</term><term>Wood (chemistry)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Bois (composition chimique)</term><term>Carbone (composition chimique)</term><term>Fibre de carbone (MeSH)</term><term>Lignine (composition chimique)</term><term>Résistance à la traction (MeSH)</term><term>Spectroscopie par résonance magnétique (MeSH)</term><term>Thermodynamique (MeSH)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Carbon</term><term>Lignin</term></keywords><keywords scheme="MESH" type="chemical" xml:lang="en"><term>Carbon Fiber</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Wood</term></keywords><keywords scheme="MESH" qualifier="composition chimique" xml:lang="fr"><term>Bois</term><term>Carbone</term><term>Lignine</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Magnetic Resonance Spectroscopy</term><term>Tensile Strength</term><term>Thermodynamics</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Fibre de carbone</term><term>Résistance à la traction</term><term>Spectroscopie par résonance magnétique</term><term>Thermodynamique</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Lignin/lignin blends were used to improve fiber spinning, stabilization rates, and properties of lignin-based carbon fibers. Organosolv lignin from Alamo switchgrass (<i>Panicum virgatum</i>) and yellow poplar (<i>Liriodendron tulipifera</i>) were used as blends for making lignin-based carbon fibers. Different ratios of yellow poplar:switchgrass lignin blends were prepared (50:50, 75:25, and 85:15 <i>w/w</i>). Chemical composition and thermal properties of lignin samples were determined. Thermal properties of lignins were analyzed using thermogravimetric analysis and differential scanning calorimetry. Thermal analysis confirmed switchgrass and yellow poplar lignin form miscible blends, as a single glass transition was observed. Lignin fibers were produced via melt-spinning by twin-screw extrusion. Lignin fibers were thermostabilized at different rates and subsequently carbonized. Spinnability of switchgrass lignin markedly improved by blending with yellow poplar lignin. On the other hand, switchgrass lignin significantly improved thermostabilization performance of yellow poplar fibers, preventing fusion of fibers during fast stabilization and improving mechanical properties of fibers. These results suggest a route towards a 100% renewable carbon fiber with significant decrease in production time and improved mechanical performance.</div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">28671571</PMID><DateCompleted><Year>2018</Year><Month>03</Month><Day>26</Day></DateCompleted><DateRevised><Year>2018</Year><Month>12</Month><Day>02</Day></DateRevised><Article PubModel="Electronic"><Journal><ISSN IssnType="Electronic">1422-0067</ISSN><JournalIssue CitedMedium="Internet"><Volume>18</Volume><Issue>7</Issue><PubDate><Year>2017</Year><Month>Jul</Month><Day>01</Day></PubDate></JournalIssue><Title>International journal of molecular sciences</Title><ISOAbbreviation>Int J Mol Sci</ISOAbbreviation></Journal><ArticleTitle>Improving Processing and Performance of Pure Lignin Carbon Fibers through Hardwood and Herbaceous Lignin Blends.</ArticleTitle><ELocationID EIdType="pii" ValidYN="Y">E1410</ELocationID><ELocationID EIdType="doi" ValidYN="Y">10.3390/ijms18071410</ELocationID><Abstract><AbstractText>Lignin/lignin blends were used to improve fiber spinning, stabilization rates, and properties of lignin-based carbon fibers. Organosolv lignin from Alamo switchgrass (<i>Panicum virgatum</i>) and yellow poplar (<i>Liriodendron tulipifera</i>) were used as blends for making lignin-based carbon fibers. Different ratios of yellow poplar:switchgrass lignin blends were prepared (50:50, 75:25, and 85:15 <i>w/w</i>). Chemical composition and thermal properties of lignin samples were determined. Thermal properties of lignins were analyzed using thermogravimetric analysis and differential scanning calorimetry. Thermal analysis confirmed switchgrass and yellow poplar lignin form miscible blends, as a single glass transition was observed. Lignin fibers were produced via melt-spinning by twin-screw extrusion. Lignin fibers were thermostabilized at different rates and subsequently carbonized. Spinnability of switchgrass lignin markedly improved by blending with yellow poplar lignin. On the other hand, switchgrass lignin significantly improved thermostabilization performance of yellow poplar fibers, preventing fusion of fibers during fast stabilization and improving mechanical properties of fibers. These results suggest a route towards a 100% renewable carbon fiber with significant decrease in production time and improved mechanical performance.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Hosseinaei</LastName><ForeName>Omid</ForeName><Initials>O</Initials><AffiliationInfo><Affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. ohossein@utk.edu.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Harper</LastName><ForeName>David P</ForeName><Initials>DP</Initials><AffiliationInfo><Affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. dharper4@utk.edu.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Bozell</LastName><ForeName>Joseph J</ForeName><Initials>JJ</Initials><AffiliationInfo><Affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. jbozell@utk.edu.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rials</LastName><ForeName>Timothy G</ForeName><Initials>TG</Initials><AffiliationInfo><Affiliation>Center for Renewable Carbon, University of Tennessee, 2506 Jacob Drive, Knoxville, TN 37996, USA. trials@utk.edu.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2017</Year><Month>07</Month><Day>01</Day></ArticleDate></Article><MedlineJournalInfo><Country>Switzerland</Country><MedlineTA>Int J Mol Sci</MedlineTA><NlmUniqueID>101092791</NlmUniqueID><ISSNLinking>1422-0067</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D000077482">Carbon Fiber</NameOfSubstance></Chemical><Chemical><RegistryNumber>7440-44-0</RegistryNumber><NameOfSubstance UI="D002244">Carbon</NameOfSubstance></Chemical><Chemical><RegistryNumber>9005-53-2</RegistryNumber><NameOfSubstance UI="D008031">Lignin</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D002244" MajorTopicYN="N">Carbon</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D000077482" MajorTopicYN="N">Carbon Fiber</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008031" MajorTopicYN="N">Lignin</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D009682" MajorTopicYN="N">Magnetic Resonance Spectroscopy</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D013718" MajorTopicYN="N">Tensile Strength</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D013816" MajorTopicYN="N">Thermodynamics</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D014934" MajorTopicYN="N">Wood</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">carbon fiber</Keyword><Keyword MajorTopicYN="N">hardwood</Keyword><Keyword MajorTopicYN="N">herbaceous</Keyword><Keyword MajorTopicYN="N">lignin</Keyword><Keyword MajorTopicYN="N">nuclear magnetic resonance (NMR) spectroscopy</Keyword><Keyword MajorTopicYN="N">tensile properties</Keyword><Keyword MajorTopicYN="N">thermal properties</Keyword><Keyword MajorTopicYN="N">thermostabilization</Keyword></KeywordList><CoiStatement>The authors declare no conflict of interest.</CoiStatement></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2017</Year><Month>04</Month><Day>18</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2017</Year><Month>06</Month><Day>22</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2017</Year><Month>06</Month><Day>27</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2017</Year><Month>7</Month><Day>4</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2017</Year><Month>7</Month><Day>4</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2018</Year><Month>3</Month><Day>27</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">28671571</ArticleId><ArticleId IdType="pii">ijms18071410</ArticleId><ArticleId IdType="doi">10.3390/ijms18071410</ArticleId><ArticleId IdType="pmc">PMC5535902</ArticleId></ArticleIdList><ReferenceList><Reference><Citation>J Agric Food Chem. 2002 Apr 10;50(8):2450-3</Citation><ArticleIdList><ArticleId IdType="pubmed">11929312</ArticleId></ArticleIdList></Reference><Reference><Citation>Biomacromolecules. 2003 May-Jun;4(3):561-7</Citation><ArticleIdList><ArticleId IdType="pubmed">12741770</ArticleId></ArticleIdList></Reference><Reference><Citation>Angew Chem Int Ed Engl. 2014 May 19;53(21):5262-98</Citation><ArticleIdList><ArticleId IdType="pubmed">24668878</ArticleId></ArticleIdList></Reference></ReferenceList></PubmedData></pubmed><affiliations><list><country><li>États-Unis</li></country><region><li>Tennessee</li></region></list><tree><country name="États-Unis"><region name="Tennessee"><name sortKey="Hosseinaei, Omid" sort="Hosseinaei, Omid" uniqKey="Hosseinaei O" first="Omid" last="Hosseinaei">Omid Hosseinaei</name></region><name sortKey="Bozell, Joseph J" sort="Bozell, Joseph J" uniqKey="Bozell J" first="Joseph J" last="Bozell">Joseph J. Bozell</name><name sortKey="Harper, David P" sort="Harper, David P" uniqKey="Harper D" first="David P" last="Harper">David P. Harper</name><name sortKey="Rials, Timothy G" sort="Rials, Timothy G" uniqKey="Rials T" first="Timothy G" last="Rials">Timothy G. Rials</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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